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The innovation process of the new alkali agent E in China

Publish Time: 2024-06-12

1. Introduction to Jinruiying (Ruying)

Jinruiying (Ruying) was established in November 2000, jointly invested by Taiwan Jinruimei Enterprise Co., Ltd. and Guangzhou Jinruiying Biotechnology Co., Ltd., with technical support from Japan Sato Chemical Co., Ltd., engaged in the development, research and production of textile auxiliaries, and provides various services for printing and dyeing factories and auxiliaries factories. With strong technical strength and a full range of products, we are committed to helping customers solve various technical problems encountered in printing and dyeing production, and continuously developing products that meet your needs. Please give us your problems, and let us use our brains for you is our service tenet.

2. Golden Eagle (Ruiying) Organization

3. Golden Eagle (Ruiying) development and research cooperation unit

4. Innovation process of Jinruiying (Ruying)'s key environmental protection, energy-saving and emission-reduction products - new alkali agent E in China

1. Research and development of new alkali agent

In addition to close cooperation with the above-mentioned colleges and universities and overseas companies, Jinruiying (Ruying) also cooperates with relevant well-known colleges and universities. Song Xinyuan, a teacher at Donghua University, and Jia Lixia, a doctoral student at Xinjiang University, have done a lot of application research on the new alkali agent E, and in 2003, under the guidance of Song Xinyuan, they were the first to publish an application paper in China. Because the technology of the new alkali agent E was infringed in China, our company was forced to publish a lawyer's statement in the "Printing and Dyeing" magazine in 2005. The content is as follows: XXX, a former employee of our company, resigned for personal reasons in December 2003 and was hired by a company in Ningbo. All technologies that he knew, used, and participated in the research and development during his employment in our company (including but not limited to the new color fixing agent E, commonly known as the substitute alkali agent or substitute alkali agent) belong to the intellectual property rights of our company and are protected by law and shall not be infringed. After XXX leaves the company (including the Ningbo company that hired him), if there is any infringement of the company's intellectual property rights or any other behavior, he will be held legally responsible upon discovery. All other behaviors of XXX after leaving the company have nothing to do with the company.

Our company successfully developed a new alkali agent E (new alkali agent S) (density 1.50, dosage is only 0.6-3.2g/L) at the beginning of its establishment in 2000.

The new alkali agent E has a narrow application range and can only dye the black color of cotton yarn. Due to continuous improvement, it has made major breakthroughs since 2003, and has been gradually improved since 2004, 2005, and 2006. It has developed a series of new alkali agent E products that are now widely welcomed by factories such as Foshan Helirong Knitting Bleaching and Dyeing Co., Ltd., Nanhai Hengxing Printing and Dyeing Co., Ltd., Minsen (Zhongshan) Textile Printing and Dyeing Co., Ltd., Guangzhou Hengfeng Printing and Dyeing Co., Ltd., Xinhui Guanhua Knitting Factory Co., Ltd., Foshan Nanfang Printing and Dyeing Factory, Zhongshan Lianhua Printing and Dyeing Co., Ltd., Qingdao Detai Thread Co., Ltd., Shandong Mingfu Dyeing Co., Ltd., Zhejiang Furun Printing and Dyeing Co., Ltd., Shaoxing County Jinxianghui Textile Printing and Dyeing Co., Ltd., Wuxi Yishun Textile Finishing Factory, Yancheng Jiangzhou Dyeing and Finishing Co., Ltd., and Yancheng Printing and Dyeing Co., Ltd. Practice has proved that the new alkali agent E (new alkali agent S) has good stability, low dosage, and meets ecological and environmental protection requirements.

2. Honors of New Alkali Agent E

On October 19, 2006, at the China National Textile and Apparel Council Science and Technology Award Ceremony held in the Great Hall of the People in Beijing, the research and development and application of New Alkali Agent E won the second prize. New Alkali Agent E fills the domestic gap and reaches the advanced level of similar international products.

On October 18, 2007, the development and application of New Alkali Agent E was included in the first batch of recommended advanced technologies for energy conservation and emission reduction in China's printing and dyeing industry.

On March 26, 2008, it was awarded the "Eleventh Five-Year Plan" Textile Industry Promotion Technology Project Certificate at the Textile Science and Technology Work Conference of the China National Textile and Apparel Council.

3. The difference between the six generations of new alkali agent E products

New alkali agent E has developed six generations of products. After the transition from the first and second generations, the third, fourth, fifth and sixth generations of products are more distinctive, and the production and application process has matured. New alkali agent E has developed six generations of products.

First generation: excellent slow dyeing, appearance: colorless transparent viscous liquid, small specific gravity, used for cotton knitting and cotton yarn;

Second generation: appearance: colorless transparent viscous liquid, used for cotton weaving, moderate specific gravity;

Third generation: appearance: orange or red liquid, used for cotton weaving, high specific gravity;

Fourth generation: appearance: colorless transparent viscous liquid, the most commonly used one by customers now, excellent reproducibility, moderate specific gravity, used for cotton knitting and cotton yarn;

Fifth generation: appearance: orange liquid, improves the red color, the darkest color, high specific gravity, used for cotton knitting, cotton yarn and cotton weaving;

Sixth generation: appearance, white powder, color light close to the depth of soda ash, strong comprehensiveness, used for cotton knitting, cotton yarn and cotton weaving.

4. Comparison of the six generations of new alkali agent E

First generation: especially suitable for fibers such as rayon and wool, with good brightness, good slow dyeing, good reproducibility, easy washing, one hot water washing and acid washing are omitted compared with the soda ash process, wet friction fastness is increased by half a level, and storage stability is good;

Second generation: especially suitable for cotton woven fabrics, suitable for long-distance use, with increased softness, and can directly replace alkali agents such as soda ash and caustic soda;

Third generation: can be used for cotton woven fabrics, with fewer washing times, great contribution to environmental protection, can reduce COD value, and fastness can be increased by half a level;

Fourth generation: dyeing black, blue, and yellow is close to the color of soda ash, caustic soda, and trisodium phosphate, with good reproducibility, good level dyeing, no batch difference and cylinder difference, easy to wash and remove, one hot water washing and acid washing are omitted compared with the soda ash process, wet friction fastness is increased by half a level, and storage stability is good;

Fifth generation: especially suitable for factories with poor water quality, red light and yellow light are heavy, blue light is slightly worse, and the overall depth is better than the fourth generation, Strong chelating power, good diffusion performance, easy to wash, omitting one hot water washing and acid washing compared to the soda ash process, and the wet friction fastness is improved by half a level;

The sixth generation: strong comprehensiveness, the color light is close to the depth of soda ash, and the sweat light fastness can be improved by half a level.

5. Issues about the use of new alkali agents

1) What are the advantages of new alkali agents compared with soda ash, caustic soda, and trisodium phosphate;

2) Comparison of various technical indicators and application performance of similar products on the market;

For example: how to correctly choose new alkali agents in powder and liquid; how to correctly distinguish new alkali agents in powder and liquid; which new alkali agent is more suitable for your printing and dyeing factory.

3) Issues that need to be paid attention to during use;

For example: how to use new alkali agents correctly, what to do if some dyes are not effective; how to prevent light color and color flowers, how to reduce costs, etc.

4) How to transition: i.e. the ratio of soda ash to substitute alkali, etc.

5) How to solve the depth and color of some sensitive colors in the process of using new alkali agents;

6) Why don’t foreign big companies produce and recommend similar products when the new alkali agents are so effective;

7) How is the quality stability of domestic new alkali agents;

8) Why are there so few large domestic printing and dyeing factories using new alkali agents?

If you encounter the above problems, please contact our technical staff directly, and our company will provide technical guidance as soon as possible.

5. Papers published by Jinruiying (Ruying)

1. 2003.No.11 "Printing and Dyeing" "Synchronous Dyeing and Fixing Process of Reactive Dyes"
①Jia Lixia, Textile Engineering College of Xinjiang University
②He Ying, Shanghai Ruiying Chemical Co., Ltd.
③Sun Hongbin, Foshan Helirong Knitting and Dyeing Co., Ltd.

2. 2005.No.5 "Dyes and Dyeing" "Study on Synchronous Dyeing of New Alkali E and Reactive Dyes"
①Zhang Liying, Chengdu Textile College
②Lian Hua, Guangdong Qihai Printing and Dyeing Co., Ltd.
③Li Zhongjing, Shandong Qingdao Jifa Group Cotton Knitting Co., Ltd.
④He Ying, Zhu Shuanghong, Shanghai Ruiying Chemical Co., Ltd.

3. 2005.No.11 "Printing and Dyeing" "Application of New Alkali E in Reactive Dyeing"
①Zhang Jianying, Textile College of Taiyuan University of Technology
②Sun Hongbin, Foshan Helirong Knitting and Dyeing Co., Ltd.
③Shanghai Ruiying Chemical Co., Ltd. He Ying, Lin Zuxia

4. 2005. No. 24 "Printing and Dyeing" "Application of New Alkali Agent E in Active Turquoise Dyeing Cotton Knitted Fabrics"
① Chengdu Textile College Zhang Liying
② Shandong Qingdao Jifa Group Cotton Knitting Co., Ltd. Li Zhongjing
③ Guangdong Textile Vocational and Technical School Wang Meiqin

5. 2006. No. 1 "Printing and Dyeing" "Application Technology of Medium-temperature Scouring Enzyme LS"
① Beijing Institute of Fashion Technology Chen Ying, Chen Sen
② Zhongshan Lianhua Printing and Dyeing Co., Ltd. Sun Hongbin

6. 2006. No. 4 "Dyes and Dyeing" "Application of New Alkali Agent E in Active Dye Dyeing"
① Beijing Institute of Fashion Technology Chen Ying, Wu Jiaojiao
② Shanghai Ruiying Chemical Co., Ltd. He Ying

7. 2006. No. 5 "Printing and Dyeing" "Application of Darkening Agent on Active Dye Dyeing Cotton Fabrics"
① Tianjin Polytechnic University School of Materials and Chemical Engineering Liu Jianyong, Xiao Jingnan
② Fujian Huiyuan Group Co., Ltd. Ye Min
③ Shanghai Ruiying Chemical Co., Ltd. He Ying

8. 2006. No. 15 "Printing and Dyeing" "Application of Deoxygenase G in Cotton Yarn Dyeing and Finishing"
① Chengdu Textile College Dong Qi, Zhang Liying
② Shanghai Ruiying Chemical Co., Ltd. He Ying

9. 2007. No. 3 "Printing and Dyeing" "Application of Medium-temperature Scouring Enzyme LS in Cotton Fabric Pretreatment"
① Chengdu Textile College Dong Qi, Zhang Liying
② Guangdong Qihai Printing and Dyeing Co., Ltd. Lian Hua
③ Shanghai Ruiying Chemical Co., Ltd. He Ying

10. 2007. No. 13 "Printing and Dyeing" "Application of Fixing Alkali Agent S in Continuous Pad Dyeing of Reactive Dyes"
① Beijing Institute of Fashion Technology Wu Jiaojiao
② Jinhua (Liya) Weaving and Dyeing Co., Ltd. Chen Qihong

11. 2008. No. 2 "Printing and Dyeing Auxiliary Agents" "Study on the Dyeing Performance of Edible Color Sunset Yellow on Cotton Fabrics"
① Qingdao University Zhang Jianbo, Yu Fei, Dong Chaohong
② Guangzhou Jinruiying Biotechnology Co., Ltd. He Ying

12, 2008. No.7 "Printing and Dyeing" "Application of New Alkali Agent E in Active Pad Dyeing Fixation"
①Changzhou Guotai Southeast Printing and Dyeing Co., Ltd. Cai Ruyue, Cao Yanfen
②Shanghai Ruiying Chemical Co., Ltd. He Ying

13, 2009. No.10 "Printing and Dyeing" "Discussion on the Application of New Alkali Agent E in Tie-Dyeing"
①Changzhou Senrong Paint Dyeing Engineering Technology Center Co., Ltd. Cai Ruyue
②Changzhou Guotai Southeast Printing and Dyeing Co., Ltd. Gao Jie
③Shanghai Ruiying Chemical Co., Ltd. He Ying

14, 2009. No.12 "Printing and Dyeing Auxiliary Agents" "Study on the Preparation and Application Performance of Alkali Substitutes"
①Qingdao University Zuo Ziyu, Zhang Jianbo, Dong Chaohong, Zhang Lin
②Guangzhou Jinruiying Biotechnology Co., Ltd. He Ying

15, 2009. No.23 "Printing and Dyeing" "Application of Salt Substitute ABE in Active Low-salt Dyeing of Cotton Fabrics"
①Beijing Institute of Fashion Technology Fang Li, Chen Ying, Zhang Yingchun
②Guangzhou Jinruiying Biotechnology Co., Ltd. He Ying

16, 2010. No.10 "Printing and Dyeing" "Treatment and Dyeing of Aramid Yarn with Modifier AB-X"
①Chengdu Textile College Zhang Liying, Zheng Guanghong, Sun Ying
②Guangzhou Jinruiying Biotechnology Co., Ltd. He Ying

17, 2010. No.15 "Printing and Dyeing" "Application of Bioenzyme S in Pretreatment of Cotton and Polyester-Cotton Fabrics"
①Hubei Huanggang Yintong Textile Co., Ltd. Wang Jinwu, Zhang Mingliang, Tu Zhiwu
②Shanghai Ruiying Chemical Co., Ltd. He Ying

18, 2010. No.20 "Printing and Dyeing" "Application of Salt Substitute ABE in Active Padding Dyeing of Cotton"
①Hubei Huanggang Yintong Textile Co., Ltd. Wang Jinwu
②Minsen (Zhongshan) Textile Printing and Dyeing Co., Ltd. Xi Daorong, Wu Shuwei
③Shanghai Ruiying Chemical Co., Ltd. He Ying

19, 2011.No.13 "Printing and Dyeing" "Application of Alkali Substitute E in Dyeing of Cotton Knitted Fabrics"
①Taiyuan University of Technology Textile Academy Zhang Jianying
②Fujian Jinjiang Longsheng Knitting Printing and Dyeing Co., Ltd. Tian Jian
③Shanghai Ruiying Chemical Co., Ltd. He Jierong

20, 2012.No.1《Printing and Dyeing》《Three-proof Finishing Agent Z-200》
①Wuhan Vocational and Technical College He Fangrong Ma Xiaoqiang
②Shanghai Ruiying Chemical Co., Ltd. He Ying

21, 2012.No.13《Printing and Dyeing》《Application of New Salt Agent A in Padding and Baking Dyeing of Reactive Dyes》
①Henan Engineering College Song Huijun
②Zhongyuan Institute of Technology Textile College Zhang Xiaoli
③Hubei Huanggang Yintong Textile Co., Ltd. Wang Jinwu
④Shanghai Ruiying Chemical Co., Ltd. He Ying

22, 2012.No.19《Printing and Dyeing》《Application of High-efficiency Scouring Enzyme LS in Pretreatment of Cotton Fabrics》
①Wuhan Vocational and Technical College He Fangrong Ma Xiaoqiang
②Shanghai Ruiying Chemical Co., Ltd. He Ying

23, 2012.No.22《Printing and Dyeing》《One-dose Scouring and Bleaching Agent LH-1》
①Wuhan Vocational and Technical College He Fangrong Guo Kaihua
② Shanghai Ruiying Chemical Co., Ltd. He Ying

24, 2013. No. 1 "Printing and Dyeing" "Technology Research on Short-Process Pretreatment Auxiliary Agent LH-I for Cotton Fabrics"
① Taiyuan University of Technology Textile Art College Zhang Jianying
② Minsen (Zhongshan) Textile Printing and Dyeing Co., Ltd. Xi Daorong
③ Shanghai Ruiying Chemical Co., Ltd. He Ying

25, 2013. No. 3 "Ningbo Chemical Industry" "A Brief Discussion on the Role of Rotten Cotton Technology in the Copying of Polyester-Cotton Fabrics"
① Taiyuan University of Technology Textile Art College Zhang Jianying
② Changzhou Dongfang Woolen Printing and Dyeing Co., Ltd. Ge Hairong
③ Shanghai Ruiying Chemical Co., Ltd. Wang Bing, He Ying

26, 2013. No. 10 "Printing and Dyeing" "Alternative Alkali Dyeing Easy EHY-703"
① Wuhan Vocational and Technical College He Fangrong
② Minsen (Zhongshan) Textile Printing and Dyeing Co., Ltd. Xi Daorong
③ Shanghai Ruiying Chemical Co., Ltd. He Ying

27, 2014. No.5 "Printing and Dyeing" "Application of Gemini Cationic Auxiliary in Cold Pad-Batch Dyeing"
① Xinjiang University Textile Engineering Institute Jia Lixia, Xiao Yuanshu, Liu Rui
② Xinjiang Fangting Knitting Co., Ltd. Zhang Huifang, Ru Jianhua
③ Shanghai Ruiying Chemical Co., Ltd. He Ying

28, 2015.No.15 "Printing and Dyeing" "Loose Cotton One-Bath Dyeing Enzyme 517 Low-Temperature One-Bath Bleaching"
① Xinjiang University Textile and Clothing College Jia Lixia, Chen Cheng
② Guangzhou Jinruiying Biotechnology Co., Ltd. He Ying

29, 2017.No.12 "Knitting Industry" "Research on the Performance of Antistatic Agent LD-5"
① Taiyuan University of Technology Textile Engineering College Zhang Jianying, Shao Fenjuan
② Qingdao University Zhang Jianbo
③ Shanxi Fiber Inspection Bureau Hu Yuzhen

6. Characteristics of new alkali agents

New alkali agent E series → for cotton, linen woven, cheese yarn, hank yarn

New alkali agent S series → for cotton, linen woven fabrics

(New alkali agent E is commonly known as substitute alkali E, substitute alkali agent, new color fixer E, active dye fixer alkali agent, color fixer E, dyeing alkali E, liquid alkali E, stable alkali E, alkali agent, accelerator, high-efficiency one-bath accelerator, etc.)

New alkali agent E series:

Used in cotton knitting, cotton cheese yarn, cotton yarn, cotton loose wool dyeing

1/8-1/10 replaces soda ash color light and soda ash color fixation effect is close

Good slow dyeing, good reproducibility

High color yield and diffusion

Reduce costs by 10%-20%

Significantly improve the brightness of cotton, especially rayon

Shorten dyeing time, wide adaptability of dyes and equipment

Storage temperature>-20 degrees, stable for more than two years, no crystallization, stratification and freezing

Reduce the repair rate by about 2%

It has obvious effect on preventing color flakes in turquoise, coffee and dark green.

It is easy to dissolve in water, easy to clean, reduces the number of washing times, and saves neutralizing acid.

It is convenient to dissolve materials and reduces labor intensity.

It can prevent embryo difference, left-middle-right, front-back color difference.

It reduces the cost of wastewater treatment.

It reduces indirect costs and reduces comprehensive costs.

New alkali agent S series:

It is used in cotton woven fabrics and is suitable for blended fabrics.

It replaces soda ash with 1/6-1/8 color light and has a color fixation effect similar to soda ash.

It has a moderate specific gravity.

It has high color yield and diffusion.

It reduces costs by 10%-20%.

It significantly improves the brightness of cotton, especially rayon.

It has a storage temperature of >-20 degrees and is stable for more than two years without crystallization, stratification and freezing.

It reduces the repair rate by about 2%.

It can prevent migration.

It is easy to dissolve in water, easy to clean, reduces the number of washing times, and saves neutralizing acid.

It is convenient to dissolve materials and reduces labor intensity.

It can prevent embryo difference, left-middle-right, front-back color difference.

It reduces the cost of wastewater treatment.

It reduces indirect costs and reduces comprehensive costs.


7. Advantages of the new alkali agent E, i.e., characteristics of the dyeing process of the new alkali agent E
1. Comparison of the dosage of soda ash and the new alkali agent E in the conventional dyeing process prescription

Dye%

≤0.5

0.5-1.0

1.0-2.0

2.0-4.0

4.0-5.0

5.0-7.0

≥7.0

Yuan Ming powder

10-20

30

40

60

60

80

100

Soda ash

4-8

12

15

20

25

35

45

New alkali agent E

0.8

1.2

1.5

2.0

3.0

4.0

5.0

Dyeing temperature: 60℃
Dyeing time: 30 minutes for dyeing promotion, 30-60 minutes for color fixation;
New alkali agent E: 10 minutes for dyeing promotion, 50-80 minutes for color fixation;
Bath ratio: 1:10
2. Effect of the new alkali agent E on dye enhancement:
K/S values of different alkali agents for deep red SDE-6BD

o.w.f.

0.5%

1%

2%

4%

6%

8%

Soda ash

4.096

9.198

16.046

24.301

29.161

31.219

Neorine E

3.601

7.135

15.532

25.426

28.625

30.410

Deep red SDE-6BD improvement curve

Golden SDE-4RD different alkali agent K/S value

o.w.f

0.5%

1%

2%

4%

6%

8%

Soda ash

3.270

5.930

11.148

18.128

22.151

24.243

Neorine E

3.257

5.709

10.458

17.222

19.548

22.231

Golden SDE-4RD lifting curve

K/S value of different alkali agents for navy blue SDE-3GD

o.w.f

0.5%

1%

2%

4%

6%

8%

Soda ash

6.394

13.260

20.958

31.162

31.328

33.508

Neorine E

6.181

12.184

18.296

30.273

31.523

35.590

Navy SDE-3GD lifting curve

Black KN-B different alkali agent K/S value

o.w.f.

0.5%

1%

2%

4%

6%

8%

Soda ash

5.099

8.930

16.908

25.780

28.704

30.668

Neorine E

5.732

8.803

16.475

27.418

29.016

32.413

Black KN-B lifting curve

Turquoise SDE-6BD different alkali agent K/S value

o.w.f.

0.5%

1%

2%

4%

6%

8%

Soda ash

4.068

9.270

15.524

23.188

27.063

30.341

Neorine E

5.141

8.038

15.314

23.186

28.112

32.717

Turquoise SDE-6BD lifting curve

From the above table, it can be seen that the new alkali agent E has the same effect on dye enhancement as soda ash, except that the enhancement of golden SDE-4RD is slightly reduced. In actual production, the dosage of the new alkali agent E can be adjusted to improve its enhancement.
3. The effect of the new alkali agent E on dyeing brightness and intensity
Using SF600 colorimeter (DATACOLOR) under D65 light source, 10º incident angle, 2%, 6% soda ash fixing agent as standard, 2%, 6% new alkali dyed cloth sample as color sample, the results are as follows:

Red SDE-6BD D65 light source

Staining depth

2%(Soda ash)

2%(New alkali agent E)

6%(Soda ash)

6%(New alkali agent E)

L

41.126

42.101

33.697

34.294

a

56.806

56.901

54.974

55.651

b

4.319

3.372

12.046

11.251

Δl

 

0.974

 

0.597

Δa

 

0.095

 

0.678

Δb

 

-0.947

 

-0.795

ΔC

 

0.031

 

0.499

ΔE

 

1.362

 

1.203

St

 

96.79

 

98.16

Visual strength

 

98

 

98

Completion

Brighter Redder Less Yellow



Golden SDE-4RD D65 light source

Staining depth

2%(Soda ash)

2%(New alkali agent E)

6%(Soda ash)

6%(New alkali agent E)

L

64.719

65.349

58.828

60.105

a

42.138

41.537

50.092

48.370

b

66.248

66.044

70.810

70.518

Δl

 

0.630

 

1.277

Δa

 

-0.601

 

-1.722

Δb

 

-0.204

 

-0.292

ΔC

 

-0.494

 

-1.224

ΔE

 

0.894

 

2.164

St

 

93.81

 

88.24

Visual strength

 

96

 

90

Completion

Brighter Less red Less yellow

 

 

Black KN-B D65 light source

Staining depth

2%(Soda ash)

2%(New alkali agent E)

6%(Soda ash)

6%(New alkali agent E)

L

27.040

27.723

17.968

18.214

a

-5.158

-5.293

-2.162

-2.395

b

-15.043

-15.777

-10.064

-10.656

Δl

 

0.683

 

0.246

Δa

 

-0.135

 

-0.233

Δb

 

-0.734

 

-0.591

ΔC

 

0.739

 

0.627

ΔE

 

1.012

 

0.681

St

 

97.43

 

101.08

Visual strength

 

96

 

98

Completion

Brighter Greener Bluer

Turquoise KN-G D65 light source

Staining depth

2%(Soda ash)

2%(New alkali agent E)

6%(Soda ash)

6%(New alkali agent E)

L

61.088

61.600

51.668

52.487

a

-33.912

-33.845

-34.682

-35.135

b

-24.265

-24.210

-27.908

-27.330

Δl

 

0.512

 

0.820

Δa

 

0.067

 

-0.453

Δb

 

0.054

 

0.578

ΔC

 

-0.086

 

-0.003

ΔE

 

0.519

 

1.100

St

 

98.64

 

103.87

Visual strength

 

96

 

100

Completion

Brighter Greener Less Blue

Navy SDE-3GD D65 light source

Staining depth

2%(Soda ash)

2%(New alkali agent E)

6%(Soda ash)

6%(New alkali agent E)

L

24.844

27.016

16.944

17.900

a

-5.198

-5.532

-1.248

-1.705

b

-16.645

-17.717

-11.897

-13.008

Δl

 

2.1712

 

0.956

Δa

 

-0.334

 

-0.458

Δb

 

-1.071

 

-1.110

ΔC

 

1.122

 

1.157

ΔE

 

2.443

 

1.100

St

 

87.29

 

100.62

Visual strength

 

88

 

98

Completion

Brighter Greener Less Blue

As can be seen from the table above, when the dosage of the new alkali agent E is low, the lightness difference ΔL of the dyed product increases, indicating that the dyeing depth of light, medium and dark dyes all show a downward trend; as the dosage of the new alkali agent E increases, this trend weakens. The intensity of the new alkali agent E is basically the same as that of pure ash after dyeing, the color is brighter, and the slight change in color is only microscopic. As the dosage of the new alkali agent E increases, the light color ΔC increases, while the medium and dark color ΔC decreases, indicating that the new alkali agent E has a certain effect on the color vividness. The dyeing depth of the new alkali agent E as a fixing agent is slightly lower than that of pure ash.

4. Color fastness comparison:

o.w.f. 2%

Alkali

Washing fastness

Dry rubbing fastness

Wet abrasion fastness

Deep Red SDE-6BD

Soda ash

4-5

4-5

3

Neorine E

4-5

4-5

3

Golden SDE-4RD

Soda ash

4

4-5

3

Neorine E

4

4-5

3

Navy SDE-3GD

Soda ash

4

4-5

3

Neorine E

4

4-5

3-4

Black KN-B

Soda ash

3-4

4-5

2-3

Neorine E

4

4-5

3

Turquoise blue KN-G

Soda ash

3-4

4-5

3

Neorine E

4

4-5

3

It can be seen from the above table that the washing resistance and wet rubbing resistance after fixation with the new alkali agent E are improved to varying degrees.

5. pH test

Alkali

Soda ash

20g/L

Neoalkali E

2g/L

Neoalkali E

2g/L

Neoalkali E

2.5g/L

Soda ash

30g/L

New E

3.2g/L

Dye solution

11.3

11.5

11.3

11.5

11.3

11.5

Dyeing residual liquid

11.3

11.3

11.3

11.4

11.4

11.2

One wash

11

10.8

11

10.8

10.8

10.7

Secondary washing

10.9

9.9

10.6

9.6

10.3

9.9

Three washes

10

8.2

9.2

8.3

10

8.9

It can be seen from the above table that after using the new alkali agent E, the pH value of the second water washing can reach the same as that of the third water washing with soda ash. It can be seen that the new alkali agent E is easy to wash and saves energy.

8. Results and Discussion:
The new alkali agent E is an optimized alkali agent for reactive dyeing process, with good buffering effect. In the process of reactive dyeing of cellulose fiber and its blends, it can replace the soda ash in the traditional process with 1/8-1/10 amount, and provide controllable synchronous dyeing and fixation. The buffer medium promotes controllable synchronous dyeing, and its buffering effect is particularly suitable for pH-sensitive dyes. Good leveling property Even for dyeing with small bath ratio, it can slow down the dyeing fixation rate. And it does not affect the color yield. For more sensitive colors, it can well overcome color flowers and layer differences (cheese dyeing). Good washing property It is very convenient to wash after dyeing (even HAC neutralization can be omitted), especially for dark colors, which can improve and enhance wet friction fastness. Even if the water quality of the dyeing plant is poor and the concentration of calcium and magnesium ions is high, there is no white spot caused by residual carbonate that cannot be washed away by soda ash. The liquid material is very convenient, improving the working environment and strength of workers, saving land for dyeing plant warehouses due to the small amount used, and facilitating warehouse storage management. Widely and efficiently applicable to various equipment, various reactive dyes and simultaneous dyeing and fixing under different bath ratio conditions. Chemical material: must be diluted with 3 times water before adding to the dye bath. If adding material to the return water, wait until the return water volume exceeds 70% and stir before adding. Adding material: can be added twice or once, and the one-time addition must be curved (rate 60-70%). If there is an automatic injection system, it can be manually controlled to be slow first and then fast, that is, only 1/3 of the material can be added in the first 2/3 of the time.
Reactive dyes are used to dye cellulose fibers, and the new alkali E is used to replace the soda ash in the traditional process. Its fixing effect is very good and the hue is relatively stable.
1/7-1/10 of the amount can be used to replace the soda ash to ensure sufficient alkalinity.
Chemical materials are easy and convenient, dispersed evenly in the dye liquor, and are not easy to produce color flowers. It is most suitable for dyeing with small bath ratios and dyeing with large molecular dyes such as turquoise.
It can be added to the dye liquor at one time to shorten the dyeing time.
It has good washability, especially for dyeing dark colors, which saves time and water, can reduce the discharge of dyeing wastewater, reduce pollution to the environment, and at the same time obtain good friction and washing fastness, and improve dyeing quality.
It is suitable for dyeing with various concentrations of reactive dyes, with good stability and reproducibility;
It does not have the problems of reduced brightness, absorption rate, discoloration, and poor reproducibility when soda ash and sodium hydroxide are used together, and there is no color flower and color instability when soda ash and trisodium phosphate are used together.
9. Product Promotion
Golden Eagle (Ruying) technical service hotline: 13925158205
13903016519


New alkali agent E (alternative alkali agent E)

Product Introduction
This product is an environmentally friendly liquid alkali substitute that our company has continuously developed and improved. On the basis of inheriting the traditional advantages of our company's new alkali agent series products with high total alkali content and strong buffering, it has excellent dyeing performance, can greatly save dyeing time and energy, and conform to the development requirements of low-carbon economy.
Technical indicators
Chemical composition: buffered organic matter
Appearance: light yellow transparent liquid
pH value (1% aqueous solution): 12-13
Solubility: easily soluble in cold water
Features
1. Used for dyeing with reactive dyes to replace sodium carbonate (soda ash).
2. High total alkali content. Under the premise of ensuring the depth of dyeing, the dosage is only 1/7 to 1/10 of soda ash.
3. Strong buffering capacity. The dyeing solution can be added at one time, and the dyeing solution maintains a stable pH from beginning to end, with good leveling and reproducibility.
4. Good solubility. Convenient material dissolution, and water washing and acid washing steps can be saved after dyeing.
5. Suitable for various dyeing equipment and processes.
Application
1. Dilute with 1:7 - 1:9 before use to equal the amount of soda ash. Do not weigh directly and add to the dye vat.
2. The amount of this product used depends on the dye system used, generally about 1-4g/L. Please confirm the color matching in the laboratory before on-site use.
3. The dyeing curve can be referred to as follows:

Note
1. This product is a strong alkaline and corrosive object, and appropriate safety measures are required. Including the use of rubber aprons and goggles to avoid contact with skin and eyes. If stained, rinse immediately with plenty of water. If clothes are stained, change them immediately and spray.
2. After dilution, it can be added directly to the dye bath without any automatic mixer or addition in batches, and no separate bath treatment is required.
3. When the color of the dark color is insufficient, 1g/L soda ash can be added in advance, or the amount of sodium sulfate can be appropriately increased (increased by about 8-12g/L), and the insulation time can also be extended by about 15-30min.
4. After the product is opened and used, it must be sealed immediately and not exposed to the air.
Instructions (please read carefully)
Customers must conduct preliminary experiments when applying, and adjust the equipment, process and prescription according to actual production conditions. If it needs to be used in combination with other additives, customers are also requested to conduct preliminary experiments to determine the appropriate additives and compounding ratios for compounding.
Health and Environmental Information
The company guarantees the safety of its products during manufacturing, transportation, handling and use, and actively provides technical support to customers. If you need detailed information about related products, please contact the company's technical department directly.

New alkali agent E-5

Product Introduction
This product is an environmentally friendly liquid alkali substitute that our company has continuously developed and improved. On the basis of inheriting the traditional advantages of our company's new alkali agent series products with high total alkali content and strong buffering, it has excellent dyeing performance, can greatly save dyeing time and energy, and conform to the development requirements of low-carbon economy.
Technical indicators
Chemical composition: buffered organic matter
Appearance: light yellow transparent liquid
pH value (1% aqueous solution): 12-13
Solubility: easily soluble in cold water
Features
1. Used for dyeing with reactive dyes to replace sodium carbonate (soda ash).
2. High total alkali content. On the premise of ensuring the depth of dyeing, the dosage is only 1/7 to 1/10 of soda ash.
3. Strong buffering capacity. The dyeing solution can be added at one time, and the dyeing solution maintains a stable pH from beginning to end, with good leveling and reproducibility.
4. Good solubility. Convenient material preparation, and water washing and acid washing steps can be saved after dyeing.
5. Applicable to various dyeing equipment and processes
Application
1. Dilute with 1:7 - 1:9 before use to equal the amount of soda ash. Do not weigh directly and add to the dye vat.
2. The amount of this product used depends on the dye system used, generally about 1-4g/L. Please confirm the color matching in the laboratory before on-site use.
3. The dyeing curve can be referred to as follows:

Note

1. This product is a strong alkaline and corrosive object, and appropriate safety measures are required. Including the use of rubber aprons and goggles to avoid contact with skin and eyes. If stained, rinse immediately with plenty of water. If clothes are stained, change them immediately and spray.

2. After dilution, it can be added directly to the dye bath without any automatic mixer or addition in batches, and no separate bath treatment is required.

3. When the color of the dark color is insufficient, 1g/L soda ash can be added in advance, or the amount of sodium sulfate can be appropriately increased (increased by about 8-12g/L), and the insulation time can also be extended by about 15-30min.

4. After the product is opened and used, it must be sealed immediately and not exposed to the air.

Instructions (please read carefully)

Customers must conduct preliminary experiments when applying, and adjust the equipment, process and prescription according to actual production conditions. If it needs to be used in combination with other additives, customers are also requested to conduct preliminary experiments to determine the appropriate additives and compounding ratios for compounding.

Health and Environmental Information

The company guarantees the safety of its products during manufacturing, transportation, handling and use, and actively provides technical support to customers. If you need detailed information about related products, please contact the company's technical department directly.


New alkali agent S (for weaving)

Product Introduction

The new alkali agent S is an environmentally friendly liquid product, easy to pump, easily soluble in cold water, suitable for pad dyeing of woven fabrics, can be directly added to the dyeing tank, and can use automatic liquid feeding system and other equipment; it can be used to replace soda ash; the new alkali agent S can reduce the inventory of soda ash, save dyeing time, reduce dyeing costs, improve dyeing quality, and reduce the rate of disease.
During the entire dyeing process using the new alkali agent S, the pH is very stable, and it has a better slow dyeing property than soda ash, so it can obtain a uniform dyeing effect, excellent dyeing repeatability (no color difference), and can shorten the dyeing time. This product has an excellent effect on black and red.
Technical indicators
Chemical composition: buffered organic matter
Appearance: light yellow viscous liquid
pH value (1% aqueous solution): 12.5±0.5
Solubility: easily soluble in cold water
Storage stability: sensitive to freezing temperature
Performance and characteristics
1. The new alkali agent S is a synthetic liquid coupling agent, which is particularly suitable for reactive dyeing of fibers. This product is used to replace soda ash.
2. Since the dye has high fixation when used on the fiber, it can obtain excellent rubbing fastness, color yield and very bright color (this is related to the control and stability of pH value during the dyeing process). There is no reduction in brightness, absorption rate or discoloration, or poor reproducibility when using NaOH, and there is no cylinder difference and color instability when using trisodium phosphate.
3. It can be used in various types of dyeing equipment, including equipment with automatic liquid feeding system. After the addition of new alkali agent S, the dye liquor can be kept in liquid form, making it easy to circulate and achieve uniform dyeing effect, without the problem of viscosity increase and difficulty in circulation of dye liquor after adding soda ash.
4. Excellent dyeing reproducibility, no batch difference and cylinder difference.
5. During the dyeing process, the pH value is always stable, with better slow dyeing than soda ash, and uniform dyeing effect can be obtained.
6. After using the new alkali agent S, the warehouse area and inventory can be reduced.
7. It is especially suitable for dyeing colors such as emerald blue, grass green, bean paste, etc. that are easy to dye, and reduce the rate of dyeing diseases.
8. Easy to wash, easy to wash away residual alkali, saving secondary washing, no alkali spots or lumps of soda ash stored at the bottom of the tank and pipelines causing re-contamination.
9. Excellent brightening effect on black and red.
Application
4. Use the weighing method to dilute 1:4 - 1:5, replace soda ash with an equal amount, do not directly weigh the new alkali agent S and add it to the dye tank.
5. The amount of new alkali agent S depends on the dye system used, generally about 1-4g/L. Please confirm the color matching in the laboratory before on-site use.
6. The dyeing process can be referred to as follows:
Rolling dyeing liquid → drying → rolling sodium sulfate, alkali solution → steaming (100℃×3min) → rinsing → drying
Note
1. The new alkali agent S is a strong alkaline and corrosive object. It should be handled with appropriate safety facilities, including rubber aprons and goggles, and avoid contact with skin and eyes. If it is stained, it should be rinsed immediately with plenty of water. If clothes are stained, they should be changed immediately
and sprayed.
2. The new alkali agent S is a buffered alkali agent for fixing reactive dyes and can be used instead of soda ash.
3. The diluted new alkali agent S can be directly added to the dye bath without any automatic mixer or batch addition, nor does it require separate bath treatment. According to our experience, if used correctly, there will be no color change, except for several special orange, red, and green dyes. Please use the dyes reasonably.
4. The new alkali agent S can be more stably controlled than strong alkali (such as sodium carbonate and sodium hydroxide) throughout the dyeing process. It can automatically supply and slowly release the required amount of alkali, and the dyeing repeatability is good.
5. There will be a small amount of precipitated material in the packaging barrel, but it will not affect the product quality.
6. After the product is opened and used, the lid must be closed immediately and not exposed to the air.
Description (please read carefully)
Since it is impossible for our company to fully understand the conditions under which its products will be used, customers must determine the appropriate process and product brand for any specific application through comprehensive tests. If it is necessary to use it in combination with other additives, customers must also determine the suitable compounding varieties and compounding ratios through tests.
Health and Environmental Information
The company guarantees the safe manufacture, transportation, handling and use of its products to provide support to customers. If you need further information about a product, please contact the company's technical department directly.

High-efficiency color fixing base EFE-3

Product Introduction
This product is an environmentally friendly liquid alkali substitute that our company has continuously developed and improved. On the basis of inheriting the traditional advantages of our company's new alkali agent series products with high total alkali content and strong buffering, it has excellent dyeing performance, can greatly save dyeing time and energy, and conform to the development requirements of low-carbon economy.
Technical indicators
Chemical composition: buffered organic matter
Appearance: white to slightly yellow powder
pH value (1% aqueous solution): 12 - 13
Solubility: soluble in cold water
Features
1. Used for dyeing with reactive dyes to replace sodium carbonate (soda ash).
2. High total alkali content. Under the premise of ensuring the depth of dyeing, the dosage is only 1/7 to 1/10 of soda ash.
3. Strong buffering capacity. The dyeing solution can be added at one time, and the dyeing solution maintains a stable pH from beginning to end, with good leveling and reproducibility.
4. Good solubility. Convenient material dissolution, and water washing and acid washing steps can be saved after dyeing.
5. Suitable for various dyeing equipment and processes.
Application
1. Dilute with 1:7 - 1:9 before use to equal the amount of soda ash. Do not weigh directly and add to the dye vat.
2. The amount of this product used depends on the dye system used, generally about 1-4g/L. Please confirm the color matching in the laboratory before on-site use.
3. The dyeing curve can be referred to as follows:

Note

1. This product is a strong alkaline and corrosive object, and appropriate safety measures are required. Including the use of rubber aprons and goggles to avoid contact with skin and eyes. If stained, rinse immediately with plenty of water. If clothes are stained, change them immediately and spray.

2. After dilution, it can be added directly to the dye bath without any automatic mixer or addition in batches, and no separate bath treatment is required.

3. When the color of the dark color is insufficient, 1g/L soda ash can be added in advance, or the amount of sodium sulfate can be appropriately increased (increased by about 8-12g/L), and the insulation time can also be extended by about 15-30min.

4. After the product is opened and used, it must be sealed immediately and not exposed to the air.

Instructions (please read carefully)

Customers must conduct preliminary experiments when applying, and adjust the equipment, process and prescription according to actual production conditions. If it needs to be used in combination with other additives, customers are also requested to conduct preliminary experiments to determine the appropriate additives and compounding ratios for compounding.

Health and Environmental Information

The company guarantees the safety of its products during manufacturing, transportation, handling and use, and actively provides technical support to customers. If you need detailed information about related products, please contact the company's technical department directly.

★★ Leading in China ★★

New alkali agent E(-5)

Product Introduction

This product is a newly developed environmentally friendly powder substitute alkali by our company. On the basis of inheriting the traditional advantages of our company's new alkali agent series products with high total alkali content and strong buffering capacity, it has excellent rapid dyeing performance, can greatly save dyeing time and energy, and conform to the development requirements of low-carbon economy.

Technical indicators

Ingredients: A mixture of inorganic compounds and organic compounds

Appearance: White powder

pH value (1% aqueous solution): 12 - 13

Solubility: Soluble in cold water, can be diluted at 1:7 - 1:9 and used in dyeing with the same amount of soda ash

Performance and characteristics

1. The new alkali agent E(-5) is a synthetic powder coupling agent, which is particularly suitable for dyeing cotton fibers with reactive dyes. This product is used to replace soda ash and is a new energy-saving and emission-reducing product.

2. It can obtain excellent dry/wet friction fastness, color uptake and bright color light, without the problems of reduced brightness and poor reproducibility when using NaOH in combination, and without the problems of cylinder difference and color instability when using trisodium phosphate in combination.

3. It can be used in various types of dyeing equipment. After the powder substitute alkali is added, the dye liquor can be kept in liquid form, making it easy to circulate and achieve a uniform dyeing effect. There is no problem that the dye liquor becomes thicker and difficult to circulate after the addition of soda ash.

4. During the dyeing process, the pH value is relatively stable compared to soda ash, and it has a better slow dyeing property than soda ash, which can obtain a uniform dyeing effect.

5. After using the new alkali agent E(-5), the warehouse area and inventory can be reduced and the workers can operate more conveniently.

6. It is especially suitable for dyeing turquoise, green, and gray series of easy-to-dye colors, reducing the rate of dyeing defects.

7. Easy to wash, easy to wash away residual alkali, which can save post-processing washing time and water consumption. There is no concern about the alkali spots or lumps of soda ash stored at the bottom of the tank and the pipeline causing re-contamination.

Application

1. Dilute it with 1:7 - 1:9 before use to equal the amount of soda ash. Do not weigh it directly and add it to the dye tank.

2. The dosage of the new alkali agent E(-5) depends on the dye system used, generally about 1-4g/L. Please confirm the color matching in the laboratory before on-site use.

3. The dyeing curve can be referred to as follows:


Note

The new alkali agent E(-5) is a strong alkaline and corrosive substance. It should be handled with appropriate safety facilities, including rubber aprons and goggles, and avoid contact with skin and eyes. If it is stained, rinse it immediately with plenty of water. If it is stained on clothes, change them immediately and spray them. The new alkali agent E(-5) is a buffered alkali agent for fixing reactive dyes and can be used instead of soda ash. The diluted new alkali agent E(-5) can be directly added to the dye bath without any automatic mixer or addition in batches, nor does it need to be treated in separate baths. According to our experience, if used correctly, there will be no color change, except for a few special orange, red, and green dyes. Please use the dyes reasonably. When dyeing medium and dark colors with the new alkali agent E(-5), if the color is too light, the amount of sodium sulfate can be appropriately increased (increase by about 8-12g/L) or the insulation time can be extended by about 15-30min. If 1g/L of sodium carbonate can be added before adding the dye, the problem of slightly lighter color retention in medium and dark colors can be basically solved. The new alkali agent E(-5) can be more stably controlled than strong alkali (such as sodium carbonate and sodium hydroxide) during the entire dyeing process. It can automatically supply and slowly release the required amount of alkali, and the dyeing repeatability is good.

After the product is opened and used, it must be sealed immediately and not exposed to the air.

Instructions (please read carefully)

Please be sure to conduct preliminary experiments when applying it, and adjust the equipment, process and prescription according to the actual production conditions. If it needs to be used in combination with other additives, please also conduct preliminary experiments to determine the appropriate additives and compounding ratios.

Health and Environmental Information

Our company's products meet the product safety standards (see MSDS data sheet for details). If you need detailed information on related products, please contact our technical department directly.

Adsorption performance of disperse dyes for polyester-cotton simultaneous dyeing on polyester_Li Haitao (1).pdf

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